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An Electrochemical Sensor for Trace Inorganic Arsenic Based on Nanoelectrode Ensembles

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Sensors

Part of the book series: Lecture Notes in Electrical Engineering ((LNEE,volume 162))

Abstract

The results of a study on the determination of trace levels of arsenic with nano-electrode ensembles (NEEs) are reported. The method is characterized by detection limit as low as 5 ng/L (65 pM) after 3 min preconcentration at −0.4 V. NEEs were applied to trace As analysis in real samples such as certified seawater samples.

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References

  1. Dai X, Nekrassova O, Hyde ME, Compton RG (2004) Anodic stripping voltammetry of arsenic(III) using gold nanoparticle-modified electrodes. Anal Chem 76:5924–5929

    Article  Google Scholar 

  2. Feeney R, Kounaves SP (2000) On-site analysis of arsenic in groundwater using a microfabricated gold ultramicroelectrode array. Anal Chem 72:2222–2228

    Article  Google Scholar 

  3. Khairy M, Kampouris DK, Kadara RO, Banks CE (2010) Gold nanoparticle modified screen printed electrodes for the trace sensing of arsenic(III) in the presence of copper(II). Electroanalysis 22:2496–2501

    Article  Google Scholar 

  4. Hossain M, Islam M, Ferdousi S, Okajima T, Ohsaka T (2008) Anodic stripping voltammetric detection of arsenic(III) at gold nanoparticle-modified glassy carbon electrodes prepared by electrodeposition in the presence of various additives. Electroanalysis 20:2435–2441

    Article  Google Scholar 

  5. Dai X, Compton RG (2006) Direct electrodeposition of gold nanoparticles onto indium tin oxide film coated glass: application to the detection of arsenic(III). Anal Sci 22:567–570

    Article  Google Scholar 

  6. Vega L, Styblo M, Patterson R, Cullen W, Wang C, Germolec D (2001) Differential effects of trivalent and pentavalent arsenicals on cell proliferation and cytokine secretion in normal human epidermal keratinocytes. Toxicol Appl Pharmacol 172:225–232

    Article  Google Scholar 

  7. Menon VP, Martin CR (1995) Fabrication and evaluation of nanoelectrode ensembles. Anal Chem 67:1920–1928

    Article  Google Scholar 

  8. Brunetti B, Ugo P, Moretto LM, Martin CR, Electroanal J (2000) Electrochemistry of phenothiazine and methylviologen biosensor electron-transfer mediators at nanoelectrode ensembles. J Electroanal Chem 491:166–174

    Article  Google Scholar 

  9. Mucelli SP, Zamuner M, Tormen M, Stanta G, Ugo P (2008) Nanoelectrode ensembles as recognition platform for electrochemical immunosensors. Biosens Bioelectron 23:1900–1903

    Article  Google Scholar 

  10. Cao L, Yan P, Sun K, Kirk DW (2009) Gold 3D brush nanoelectrode ensembles with enlarged active area for the direct voltammetry of daunorubicin. Electroanalysis 21:1183–1188

    Article  Google Scholar 

  11. Ugo P, Moretto LM, Silvestrini M, Pereira FC (2010) Nanoelectrode ensembles for the direct voltammetric determination of trace iodide in water. Int J Environ Anal Chem 90:747–759

    Article  Google Scholar 

  12. Leo MD, Pereira FC, Moretto LM, Scopece P, Polizzi S, Ugo P (2007) Towards a better understanding of gold electroless deposition in track-etched templates. Chem Mater 19: 5955–5964

    Article  Google Scholar 

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Correspondence to P. Ugo .

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Mardegan, A., Scopece, P., Moretto, L.M., Ugo, P. (2014). An Electrochemical Sensor for Trace Inorganic Arsenic Based on Nanoelectrode Ensembles. In: Baldini, F., et al. Sensors. Lecture Notes in Electrical Engineering, vol 162. Springer, New York, NY. https://doi.org/10.1007/978-1-4614-3860-1_81

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  • DOI: https://doi.org/10.1007/978-1-4614-3860-1_81

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  • Publisher Name: Springer, New York, NY

  • Print ISBN: 978-1-4614-3859-5

  • Online ISBN: 978-1-4614-3860-1

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