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An electroanalytical investigation of the olefin isomerization reaction promoted by electrogenerated cationic nickel(I) complexes

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Summary

Evidence for the ability of the electrogenerated cationic nickel(I) complex [Ni(PPh3)4]+ to promote the isomerization of allylbenzene is reported. However, the corresponding triethylphosphitenickel(I) complex displays no catalytic activity, apparently due to the poor leavinggroup character exhibited by the phosphite. The involvement of a π-allylnickel hydride in the isomerization reaction is inferred from a comparison of the results obtained with those for the same reaction promoted by nickel hydride.

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Authors and Affiliations

  1. Institute of Chemistry, University of Udine, Viale Ungheria 43, 33100, Udine, Italy

    Gino Bontempelli

  2. Department of Spectroscopy, Electrochemistry and Physical Chemistry, University of Venezia, Dorsoduro 2137, 30123, Venezia, Italy

    Salvatore Daniele

  3. C.N.R., Institute of Polarography and Preparative Electrochemistry, Corso Stati Uniti 4, 35100, Padova, Italy

    Gilberto Schiavon

  4. Department of Inorganic, Metallorganic and Analytical Chemistry, University of Padova, Via Marzolo 1, 35131, Padova, Italy

    Mario Fiorani

Authors
  1. Gino Bontempelli
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  2. Salvatore Daniele
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  3. Gilberto Schiavon
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  4. Mario Fiorani
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Bontempelli, G., Daniele, S., Schiavon, G. et al. An electroanalytical investigation of the olefin isomerization reaction promoted by electrogenerated cationic nickel(I) complexes. Transition Met Chem 12, 292–295 (1987). https://doi.org/10.1007/BF01024015

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  • DOI: https://doi.org/10.1007/BF01024015

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