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CO Preferential Oxidation Activity of CuO/CeO2 Supported on Zirconium Doped Mesoporous MSU Type Silica

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Abstract

The activity of the CuO–CeO2 couple supported on a MSU silica doped with zirconium (Si/Zr = 7), was evaluated in the preferential oxidation of CO (CO-PROX) in hydrogen-rich gas stream (1.2% CO, 1.2% O2, 50% H2, 0–15% CO2, 0–10% H2O He balance) and the catalytic performance was compared with that of CuO–CeO2 supported on a pure MSU silica. The samples were characterized by X-ray powder diffraction (XRPD), N2 physisorption at 77 K, temperature-programmed reduction (H2-TPR) and X-ray photoelectron spectroscopy (XPS). Correlations between catalytic performances and physico–chemical properties of the materials have been made.

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Acknowledgments

The Ministero dell’Università e Ricerca (MiUR-PRIN 2006) is gratefully acknowledged for financial support by the Italian authors. The Spanish authors thanks the Project NAN2004-09267-C03-01 (Ministerio de Educacion y Ciencia, Spain).

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Authors and Affiliations

  1. INSTM UdR Venezia – Dipartimento di Chimica, Università Ca’ Foscari di Venezia, Via Torino 155/B, 30172, Mestre Venezia, Italy

    Elisa Moretti, Loretta Storaro, Aldo Talon & Maurizio Lenarda

  2. Departamento de Química Inorgánica, Cristalografía y Mineralogía (Unidad Asociada al ICP-CSIC), Facultad de Ciencias, Universidad de Málaga, Campus de Teatinos, E-29071, Málaga, Spain

    Ramón Moreno-Tost, Enrique Rodríguez-Castellón & Antonio Jiménez-López

Authors
  1. Elisa Moretti
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  2. Loretta Storaro
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  3. Aldo Talon
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  4. Ramón Moreno-Tost
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  5. Enrique Rodríguez-Castellón
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  6. Antonio Jiménez-López
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  7. Maurizio Lenarda
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Correspondence to Maurizio Lenarda.

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Moretti, E., Storaro, L., Talon, A. et al. CO Preferential Oxidation Activity of CuO/CeO2 Supported on Zirconium Doped Mesoporous MSU Type Silica. Catal Lett 129, 323–330 (2009). https://doi.org/10.1007/s10562-009-9858-5

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  • DOI: https://doi.org/10.1007/s10562-009-9858-5

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