Abstract
An authentication study of the Italian PDO (protected designation of origin) olive oil Chianti Classico, based on near-infrared and UV–Visible spectroscopy, an artificial nose and an artificial tongue, with a set of samples representative of the whole Chianti Classico production and a considerable number of samples from a close production area (Maremma) was performed. The non-specific signals provided by the four fingerprinting analytical techniques, after a proper pre-processing, were used for building class models for Chianti Classico oils. The outcomes of classical class-modelling techniques like soft independent modelling of class analogy and quadratic discriminant analysis—unequal dispersed classes were compared with those of two techniques recently introduced into Chemometrics: multivariate range modelling and CAIMAN analogues modelling methods.
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Luykx DMAM, van Ruth SM (2008) Food Chem 107:897–911
Dimara E, Skuras D (2003) Eur J Market 37:690–705
European Council Regulation No 510/2006 of 20 Mar 2006
European Commission Regulation No 2446/2000 of 6 Nov 2000
Ministero delle Politiche Agricole e Forestali, Provvedimento of 4 Dec 2000, Gazzetta Ufficiale della Repubblica Italiana No 13 of 17 Jan 2001
Armanino C, Leardi R, Lanteri S, Modi G (1989) Chemom Intell Lab Syst 5:343–354
Ollivier D, Artaud J, Pinatel C, Durbec JP, Guérère M (2006) Food Chem 97:382–393
Lerma-García MJ, Herrero-Martínez JM, Ramis-Ramos G, Simó-Alfonso EF (2008) Food Chem 108:1142–1148
Valcárcel M, Cárdenas S (2005) Trends Anal Chem 24:67–74
Sinelli N, Casiraghi E, Tura D, Downey G (2007) J Near Infrared Spectrosc 16:335–342
Forina M, Boggia R, Casale M (2007) Ann Chim (Rome) 97:615–633
Cosio MS, Ballabio D, Benedetti S, Gigliotti C (2006) Anal Chim Acta 567:202–210
Oliveri P, Baldo MA, Daniele S, Forina M (2009) Anal Bioanal Chem 395:1135–1143
Forina M, Oliveri P, Lanteri S, Casale M (2008) Chemom Intell Lab Syst 93:132–148
Cerrato-Oliveros C, Boggia R, Casale M, Armanino C, Forina M (2005) J Chromatogr A 1076:7–15
Barnes RJ, Dhanoa MS, Lister SJ (1989) Appl Spectrosc 43:772–777
Jolliffe IT (2002) Principal component analysis. Springer series in statistics, 2nd edn. Springer, New York
Wold S, Sjöström M (1977) Chemometrics: theory and applications. In: Kowalski BR (ed) Chemometrics: theory and application, ACS Symposium Series 52. American Chemical Society, Washington, pp 243–282
Hotelling H (1947) Multivariate quality control. In: Eisenhart C, Hastay MW, Wallis WA (eds) Techniques of statistical analysis. McGraw-Hill, New York, pp 111–184
Derde MP, Massart DL (1986) Anal Chim Acta 184:33–51
Forina M, Oliveri P, Casale M, Lanteri S (2008) Anal Chim Acta 622:85–93
Forina M, Casale M, Oliveri P, Lanteri S (2009) Chemom Intell Lab Syst 96:239–245
Forina M, Lanteri S, Armanino C, Casolino C, Casale M, Oliveri P (2009) V-PARVUS 2009, University of Genoa, Genoa. http://www.parvus.unige.it. Accessed 2 Jan 2010
Harper AM, Duewer DL, Kowalski BR, Fashing JL (1977) In: Kowalski BR (ed) Chemometrics: theory and application, ACS Symposium Series 52. American Chemical Society, Washington, pp 14–52
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Financial support by the Italian Ministry of University and Research (MIUR) and by the University of Genoa is gratefully acknowledged.
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Published in the special issue Chemometrics (VII Colloquium Chemiometricum Mediterraneum) with Guest Editors Marcelo Blanco, Juan M. Bosque-Sendra and Luis Cuadros-Rodríguez.
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Oliveri, P., Casale, M., Casolino, M.C. et al. Comparison between classical and innovative class-modelling techniques for the characterisation of a PDO olive oil. Anal Bioanal Chem 399, 2105–2113 (2011). https://doi.org/10.1007/s00216-010-4377-1
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DOI: https://doi.org/10.1007/s00216-010-4377-1