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Synthesis, Characterization and Catalytic Activity of a Tungsten(VI) Amino Triphenolate Complex

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Abstract

Synthesis, characterization and catalytic activity of a novel tungsten(VI) amino triphenolate complex have been investigated. In particular, a tungsten(VI) amino triphenolate complex has been synthesized and tested in the oxidation of sulfides and cyclooctene, using hydrogen peroxide as terminal oxidant. The catalyst has proved to be air and water tolerant, also showing a good efficiency in terms of yields and selectivity. Moreover, an upgrade of our previous ligand synthesis is herein reported. The new developed procedure allows to obtain the triphenolamine in large scale without the use of chromatography for the intermediates purification.

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Acknowledgements

This research was supported by Università di Padova (PRAT- CPDA153122) and Cariparo Foundation (F.R. fellowship). The project has been carried out in the frame of Cost Action CM1402—Crystallize.

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Authors and Affiliations

  1. Dipartimento di Scienze Chimiche and CIRCC, Università di Padova, via Marzolo 1, 35131, Padua, Italy

    Elena Badetti, Alessandro Bonetto, Francesco Romano, Cristiano Zonta & Giulia Licini

  2. Dipartimento di Chimica, Università degli Studi di Parma, Viale delle Scienze 17/A, 43123, Parma, Italy

    Luciano Marchiò

Authors
  1. Elena Badetti
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  2. Alessandro Bonetto
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  3. Francesco Romano
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  4. Luciano Marchiò
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  5. Cristiano Zonta
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  6. Giulia Licini
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Corresponding authors

Correspondence to Cristiano Zonta or Giulia Licini.

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Badetti, E., Bonetto, A., Romano, F. et al. Synthesis, Characterization and Catalytic Activity of a Tungsten(VI) Amino Triphenolate Complex. Catal Lett 147, 2313–2318 (2017). https://doi.org/10.1007/s10562-017-2144-z

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  • DOI: https://doi.org/10.1007/s10562-017-2144-z

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