Abstract
Surfactant is a special kind of amphiphilic compound composed of water-loving and hating parts. The remarkable physical properties like interfacial tension, wettability, emulsifying and dispersing ability make the surfactant accessible for numerous applications from laboratory to commercial products. In recent years, the commercial applications of surfactant have led to greater relevance on account of the environmental concerns and market pressures of this compound. The utility of surfactants in global market increases steadily since its formulation with several beneficial aspects in pharmaceutical, detergent, cosmetic, paint, food science, gas hydrate, nanotechnology, petroleum recovery, bioremediation, chemical transformation and drug delivery. This review briefly discusses the applied aspect of surfactants in diverse area as well as catalytic effect of micelle in organic reactions from the recent literature survey. The trend of increasing use of bioderived surfactants in the modern field of research is also considered in this report. The recent advancement of surfactant-based organic transformations has been emphasized with the role of surfactant aggregates in course of different organic reactions.







Similar content being viewed by others
Abbreviations
- CTADC:
-
Cetyltrimethylammonium dichromate
- CTAB:
-
Cetyltrimethylammonium bromide
- SDS:
-
Sodium dodecyl sulfate
- TTAB:
-
Tetradecyltrimethylammonium bromide
- CHAPS:
-
3-[(3-Cholamidopropyl)dimethylammonio]-1-propanesulfonate
- CPC:
-
N-cetylpyridinium chloride
- Brij 35:
-
Dodecyltricosaethylene glycol ether
- Tween-80:
-
Polyethylene oxide sorbitan monooleate
- Span 20:
-
Sorbitan monolaurate
- Span 40:
-
Sorbitan monopalmitate
- SDBS:
-
Sodium dodecylbenzenesulfonate
- CMC:
-
Critical micellar concentration
- DODAB:
-
Dioctadecyldimethylammonium bromide
- DMPC:
-
Dimyristoylphosphatidylcholine
- CD:
-
Cyclodextrin
References
P.J. Reeve, H.J. Fallowfield, J. Environ. Manag. 205, 253 (2018)
V. Hamme, J.D. Singh, A. Ward, Biotechnol. Adv. 24, 604 (2006)
M. Bustamante, N. Duran, M.C. Diez, J. Soil Sci. Plant Nutr. 12, 667 (2012)
J. Zhao, X. Liu, Y. Wu, D.-S. Li, Q. Zhang, Coord. Chem. Rev. 391, 30 (2019)
M. Ramanathan, L.K. Shrestha, T. Mori, Q. Ji, J.P. Hill, K. Ariga, Phys. Chem. Chem. Phys. 15, 10580 (2013)
A. Spernath, A. Aserin, Adv. Colloid Interface Sci. 128–130, 47 (2006)
M. Fanun, Curr. Opin. Colloid Interface Sci. 17, 306 (2012)
S. Chowdhury, A. Rakshit, A. Acharjee, B. Saha, ChemistrySelect 4, 6978 (2019)
J. Eastoe, M.J. Hollamby, L. Hudson, Adv. Colloid Interface Sci. 128–130, 5 (2006)
A.S. Narang, D. Delmarre, D. Gao, Int. J. Pharm. 345, 9 (2007)
M. Mishra, P. Muthuprasanna, K. Surya Prabha, P. Sobhitarani, I.A. Satishbabu, I.S. Chandiran, G. Arunachalam, S. Shalini, Int. J. PharmTech Res. 1, 1354 (2009)
M.H. Mondal, S. Malik, A. Roy, R. Saha, B. Saha, RSC Adv. 5, 92707 (2015)
C.N. Mulligan, Environ. Pollut. 133, 183 (2005)
Z. Huang, C. Cheng, L. Li, Z. Guo, G. He, X. Yu, R. Liu, H. Han, L. Deng, W. Fu, J. Agric. Food Chem. 66, 13126 (2018)
M.H. Mondal, A. Roy, S. Malik, A. Ghosh, B. Saha, Res. Chem. Intermed. 42, 1913 (2016)
S. De, S. Malik, A. Ghosh, R. Saha, B. Saha, RSC Adv. 5, 65757 (2015)
M. Schwarze, T. Pogrzeba, I. Volovych, R. Schomacker, Catal. Sci. Technol. 5, 24 (2015)
C.H. Hsu, Z. Cui, R.J. Mumper, M. Jay, AAPS PharmSciTech 9, 939 (2008)
A. Al-Lohedan, H.F.F. Al-Blewi, M.Z.A. Rafiquee, Z.A. Issa, J. Mol. Liq. 206, 321 (2015)
A.S. Al-Ayed, M. Ali, H.A. Al-Lohedan, A.M. Al-Sulaim, Z.A. Issa, J. Colloid Interface Sci. 361, 205 (2011)
C. De, R. Saha, S.K. Ghosh, A. Ghosh, K. Mukherjee, S.S. Bhattacharyya, B. Saha, Res. Chem. Intermed. 39, 3463 (2013)
S. Mandal, S. Mandal, S. Biswas, S. Banerjee, B. Saha, Res. Chem. Intermed. 44, 2169 (2017)
P. Sar, A. Ghosh, S. Malik, B. Saha, J. Carbohydr. Chem. 35, 86 (2016)
M. Ishiguro, L.K. Koopal, Adv. Colloid Interface Sci. 23, 59 (2016)
T. Dwars, E. Paetzold, G. Oehme, Angew. Chem. Int. Ed. 44, 7174 (2005)
Market Report: Global Surfactant Market, 4th edition
B.S. Sekhon, J. Pharm. Technol. Res. Manag. 1, 11 (2013)
N. Kumar, R. Tyagi, Cosmetics 1, 3 (2014)
C. Zhou, F. Wang, H. Chen, M. Li, F. Qiao, Z. Liu, Y. Hou, C. Wu, Y. Fan, L. Liu, S. Wang, Y. Wang, A.C.S. Appl, Mater. Interfaces 8, 4242 (2016)
M. Lukic, I. Pantelic, S. Savic, Tenside Surfactant Det. 53, 7 (2016)
M. Jadhav, R.S. Kalhapure, S. Rambharose, C. Mocktar, T. Govender, J. Ind. Eng. Chem. 47, 405 (2016)
R. Herbert, D. Tom, S. Anja, G. Silke, B. Harald, Am. J. Rhinol. 18, 291 (2004)
R. Enomoto, C. Suzuki, M. Ohno, T. Ohasi, R. Futagami, K. Ishikawa, M. Komae, T. Nishino, Y. Konishi, E. Lee, Ann. N. Y. Acad. Sci. 1095, 1 (2007)
M.C. Moran, A. Pinazo, L. Perez, P. Clapes, M. Angelet, M.T. Garcia, M.P. Vinardell, M.R. Infante, Green Chem. 6, 233 (2004)
A. Pinazo, R. Pons, L. Perez, M.R. Infante, Ind. Eng. Chem. Res. 50, 4805 (2011)
A. Pinazo, M.A. Manresa, A.M. Marques, M. Bustelo, M.J. Espuny, L. Perez, Adv. Colloid Interface Sci. 228, 17 (2016)
L.S. Jones, N.B. Bam, T.W. Randolph, ACS Symp. Ser. 675, 206 (1997)
T.W. Randolph, L.S. Jones, Surfactant-protein interactions, in Pharmaceutical Biotechnology, Rational Design of Stable Protein Formulations, vol. 13, ed. by J.F. Carpenter, M.C. Manning (Plenum, New York, 2002), p. 159
H.L. Kim, A. Mcauley, J. Mcguire, J. Pharm. Sci. 103, 1337 (2014)
P.K. Chang, C.A. Prestidge, T.J. Barnes, K.E. Bremmell, RSC Adv. 6, 78970 (2016)
J.S. Katz, Y. Tan, K. Kuppannan, Y. Song, D.J. Brennan, T. Young, L. Yao, S. Jordan, A.C.S. Biomater, Sci. Eng. 2, 1093 (2016)
T.A. Khan, H.-C. Mahler, R.S.K. Kishore, Eur. J. Pharm. Biopharm. 97, 60 (2015)
B.A. Kerwin, J. Pharm. Sci. 97, 2924 (2008)
M. Agarkhed, C. O’Dell, M.-C. Hsieh, J. Zhang, J. Goldstein, A. Srivastava, AAPS PharmSciTech 14, 1 (2013)
A. Martos, W. Koch, W. Jiskoot, K. Wuchner, G. Winter, W. Friess, A. Hawe, J. Pharm. Sci. 106, 1722 (2017)
L. Landeck, L.A. Baden, S.-M. John, Detergents, in Kanervas Occupational Dermatology, vol. 2, 2nd edn., ed. by T. Rustemeyer, P. Elsner, S.M. John, H. Maibach (Springer, Berlin, 2012), p. 847
L.L. Schramm, E.N. Stasiuk, D.G. Marangoni, Annu. Rep. Prog. Chem. Sect. C Phys. Chem. 99, 3 (2003)
D. Bajpai, V.K. Tyagi, J. Oleo Sci. 56, 327 (2007)
J.J. Scheibel, J. Surfactants Deterg. 7, 319 (2004)
Chemical Formulation: An Overview of Surfactant-based Preparations Used in Everyday Life, Chapter 2: Surfactants in Action, RSC (2003) Cambridge University Press, Cambridge, UK, p. 71
M. Saraji, N. Shirvani, Int. J. Cosmet. Sci. 39, 36 (2017)
C.M.S. Reis, E. Reis-Filho, Cleanser, in Clinical Approaches and Procedures in Cosmetic Dermatology, ed. by M.C.A. Issa, B. Tamura (Springer, New York, 2016), p. 1
H. Biniciet, Res. Civil Environ. Eng. 1, 169 (2013)
M.I. Levison, in Handbook of Detergents Part E: Applications, ed., Taylor & Francis Group, LLC, 2009
R. Nandi, S. Laskar, B. Saha, Res. Chem. Intermed. 43, 1619 (2017)
K. Mukherjee, D. Ghosh, B. Saha, Des. Water Treat. 57, 169219 (2016)
M.H. Mondal, S. Malik, A. Garain, S. Mandal, B. Saha, Tenside Surfactant Det. 54, 519 (2017)
K. Mukherjee, R. Saha, A. Ghosh, S.K. Ghosh, P.K. Maji, B. Saha, Res. Chem. Intermed. 40, 1727 (2014)
K. Mukherjee, R. Nandi, D. Saha, B. Saha, Des. Water Treat. 54, 525 (2015)
K. Mukherjee, R. Saha, A. Ghosh, B. Saha, Res. Chem. Intermed. 39, 2267 (2013)
K. Mukherjee, D. Ghosh, B. Saha, Tenside Surfactant Det. 51, 521 (2014)
F. Fava, S. Berselli, P. Conte, A. Piccolo, L. Marchetti, Biotechnol. Bioeng. 88, 214 (2004)
Y. Cheng, H. He, C. Yang, Z. Yan, G. Zeng, H. Qian, Chemosphere 150, 248 (2016)
W.C. Chan, H.Z. You, Afr. J. Biotechnol. 9, 5914 (2010)
W.J. Zhou, J.J. Yang, L.Z. Zhu, Environ. Pollut. 159, 1198 (2011)
S.S. Cameotra, R.S. Makkar, J. Kaur, S.K. Mehta, Biosurfactants, vol. 20 (Springer, New York, 2010), p. 261
F. Bassyouni, N. ElHalwany, M.A. Rehim, M. Neyfeh, Res. Chem. Intermed. 41, 2165 (2015)
A. Aumelas, A. Serrero, A. Durand, E. Dellacherie, M. Leonard, Colloids Surf. B 59, 74 (2007)
Y. Cheng, Q. Wu, Y. Li, J. Hu, T. Xu, J. Phys. Chem. B 113, 8339 (2009)
D. Kumar, N. Azum, M.A. Rub, A.M. Asiri, J. Mol. Liq. 262, 86 (2018)
R.C.F.G. Lopes, O.F. Silvestre, A.R. Faria, M.L.C. do Vale, E.F. Marques, J.B. Nieder, Nanoscale 11, 5932 (2019)
A.V. Solomonov, Y.S. Marfin, E.V. Rumyantsev, E. Ragozin, T. Shekhter, Z.G. Gellerman, A.B. Tesler, F. Muench, A. Kumagai, A. Miyawak, Mat. Sci. Eng. C 99, 794 (2019)
P. Balakrishnan, S. Shanmugam, W.S. Lee, W.M. Lee, J.O. Kim, D.H. Oh, D.-D. Kim, J.S. Kim, B.K. Yoo, H.-G. Choi, J.S. Woo, C.S. Yong, Int. J. Pharm. 377, 1 (2009)
K. Hayashi, H. Iwai, T. Kamei, K. Iwamoto, T. Shimanouchi, S. Fujita, H. Nakamura, H. Umakoshi, Colloids Surf. B 152, 269 (2017)
E.N. Donders, A.N. Ganesh, H. Torosyan, P. Lak, B.K. Shoichet, M.S. Shoichet, ACS Chem. Biol. 14, 1507 (2019)
F. Zhang, M.S. Islam, R.M. Berry, K.C. Tam, ACS Omega 4, 2102 (2019)
B. Hu, Y. Yuan, Y. Yan, X. Zhou, Y. Li, Q. Kan, S. Li, Mater. Sci. Eng. C 75, 637 (2017)
P. Laskar, B. Saha, S.K. Ghosh, J. Dey, RSC Adv. 5, 16265 (2015)
M. Salim, H. Minamikawa, A. Sugimura, R. Hashim, Med. Chem. Commun. 5, 1602 (2014)
S. Mandal, S. Mandal, S.K. Ghosh, P. Sar, A. Ghosh, R. Saha, B. Saha, RSC Adv. 6, 69605 (2016)
P. Sar, A. Ghosh, S. Malik, D. Ray, B. Das, B. Saha, J. Ind. Eng. Chem. 42, 53 (2016)
R. Saha, A. Ghosh, P. Sar, I. Saha, S.K. Ghosh, K. Mukherjee, B. Saha, Spectrochim. Acta Part A 116, 524 (2013)
P. Sar, A. Ghosh, R. Saha, B. Saha, Res. Chem. Intermed. 41, 5331 (2015)
P. Sar, A. Ghosh, D. Ghosh, B. Saha, Res. Chem. Intermed. 41, 5565 (2015)
A. Ghosh, R. Saha, K. Mukherjee, S.K. Ghosh, P. Sar, S. Malik, B. Saha, Res. Chem. Intermed. 41, 3057 (2015)
A. Ghosh, P. Sar, S. Malik, B. Saha, J. Mol. Liq. 211, 48 (2015)
P. Sar, A. Ghosh, B. Saha, Res. Chem. Intermed. 41, 7775 (2015)
S. Chowdhury, A. Rakshit, A. Acharjee, A. Ghosh, K. Mahali, B. Saha, J. Mol. Liq. 290, 111247 (2019)
P. Sar, A. Ghosh, S. Malik, B. Saha, Res. Chem. Intermed. 41, 10151 (2015)
A. Ghosh, P. Das, D. Saha, P. Sar, S.K. Ghosh, B. Saha, Res. Chem. Intermed. 42, 2619 (2016)
A. Ghosh, K. Sengupta, R. Saha, B. Saha, J. Mol. Liq. 198, 369 (2014)
P.K. Sen, N. Gani, J.K. Midya, B. Pal, Int. J. Chem. Kinet. 44, 482 (2012)
R. Shukla, S.K. Upadhyay, Colloids Surf. A 331, 245 (2008)
S. Garnayak, S. Patel, Int. J. Chem. Kinet. 48, 32 (2016)
Y.R. Katre, S. Nayak, D.N. Sharma, A.K. Singh, Res. Chem. Intermed. 38, 179 (2012)
G.L. Sorella, G. Strukul, A. Scarso, Green Chem. 17, 644 (2015)
T. Kitanosono, K. Masuda, P. Xu, S. Kobayashi, Chem. Rev. 118, 679 (2018)
B.H. Lipshutz, S. Ghorai, M. Cortes-Clerget, Chem. Eur. J. 24, 6672 (2018)
A. Scarso, Micellar nanoreactors, in Encyclopedia of Inorganic and Bioinorganic Chemistry, 1–16 edn., ed. by D.A. Atwood (Wiley, Chichester, 2016)
A. Scarso, G. Strukul, Transition metal catalysis in micellar media: much more than a simple green chemistry promise, in Green Synthetic Processes and Procedures, ed. by R. Ballini (RSC, New York, 2019), p. 268
D. Paprocki, A. Madej, D. Koszelewski, A. Brodzka, R. Ostaszewski, Front. Chem. 6, 502 (2018)
B.H. Lipshutz, Curr. Opin. Green Sust. Chem. 11, 1 (2018)
M. Bihani, T.N. Ansari, J.D. Smith, S. Handa, Curr. Opin. Green Sust. Chem. 11, 45 (2018)
A. Eivazihollagh, I. Svanedal, H. Edlund, M. Norgren, J. Mol. Liq. 278, 688 (2019)
M.-J. Bu, G.-P. Lu, J. Jiang, C. Cai, Catal. Sci. Technol. 8, 3728 (2018)
S. Polarz, M. Kunkel, A. Donner, M. Schlotter, Chem. Eur. J. 24, 18842 (2018)
K. Ravi, B.D. Bankar, S. Jindani, A.V. Biradar, ACS Omega 4, 9453 (2019)
A. Acharjee, A. Rakshit, S. Chowdhury, S. Malik, M.K. Barman, M. Ali, B. Saha, J. Mol. Liq. 277, 360 (2019)
A. Acharjee, A. Rakshit, S. Chowdhury, I. Datta, M.K. Barman, M. Ali, B. Saha, J. Mol. Liq. 293, 111475 (2019)
A. Chakraborty, T. Ghosh, D.K. Maiti, S. Majumdar, ChemistrySelect 4, 1841 (2019)
Y. Suzaki, Y. Kobayashi, Y. Tsuchido, K. Osakada, Mol. Catal. 466, 106 (2019)
M. Schmidt, S. Schreiber, L. Franz, H. Langhoff, A. Farhang, M. Horstmann, H.-J. Drexler, D. Heller, M. Schwarze, Ind. Eng. Chem. Res. 58, 2445 (2019)
G.L. Sorella, L. Sperni, P. Canton, L. Coletti, F. Fabris, G. Strukul, A. Scarso, J. Org. Chem. 14, 7438 (2018)
S. Tang, L. Li, X. Ren, J. Li, G. Yang, H. Li, B. Yuan, Green Chem. 21, 2899 (2019)
X. Bai, X. Huang, L. Wen, N. Song, J. Zhang, Y. Zhang, Y. Zhao, Chem. Commun. 55, 3598 (2019)
S.R. Yetra, T. Rogge, S. Warratz, J. Struwe, W. Peng, P. Vana, L. Ackermann, Angew. Chem. Int. Ed. 58, 7490 (2019)
M. Cortes-Clerget, N.R. Lee, B.H. Lipshutz, Nat. Protoc. 14, 1108 (2019)
M. Cortes-Clerget, N. Akporji, J. Zhou, F. Gao, P. Guo, M. Parmentier, F. Gallou, J.-Y. Berthon, B.H. Lipshutz, Nat. Commun. 10, 2169 (2019)
H. Pang, F. Gallou, H. Sohn, J. Camacho-Bunquin, M. Delferro, B.H. Lipshutz, Green Chem. 20, 130 (2018)
D. Chen, Y. Zhang, X. Pan, F. Wang, S. Huanga, Adv. Synth. Catal. 360, 3607 (2018)
S. Handa, F. Ibrahim, T.N. Ansari, F. Gallou, ChemCatChem 10, 4229 (2018)
M. Cortes-Clerget, S.E. Spink, G.P. Gallagher, L. Chaisemartin, E. Filaire, J.-Y. Berthonb, B.H. Lipshutz, Green Chem. 21, 2610 (2019)
N.R. Lee, M. Cortes-Clerget, A.B. Wood, D.J. Lippincott, H. Pang, F.A. Moghadam, F. Gallou, B.H. Lipshutz, ChemSusChem 12, 3159 (2019)
G. NikhilVaidya, S. Fiske, H. Verma, S.K. Lokhande, D. Kumar, Green Chem. 21, 1448 (2019)
Author information
Authors and Affiliations
Corresponding authors
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Sar, P., Ghosh, A., Scarso, A. et al. Surfactant for better tomorrow: applied aspect of surfactant aggregates from laboratory to industry. Res Chem Intermed 45, 6021–6041 (2019). https://doi.org/10.1007/s11164-019-04017-6
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11164-019-04017-6
Keywords
Profiles
- Pintu Sar View author profile