Skip to main content
Log in

An Improved Method for the Preparation of Tetra-Coordinate Platinum(II) Chloro-Complexes Containing Bidentate or Terdentate Ligands Starting from cis/trans-[PtCl2(SMe2)2]

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Abstract

An improved method for the preparation of differently charged chelate Pt(II) chloro-complexes is reported. All the complexes have been obtained rapidly and in high yield, by simply reacting equimolar amounts of cis/trans- dichlorobis(dimethylsulphide)platinum(II) with the chelate ligand in an appropriate solvent (CH2Cl2, MeOH or H2O). The ligands chosen were: 1,2-bis(diphenylphosphino)ethane (P—P), pyridine–2-carboxylate (N—O), 2-[(methylthio)methyl]pyridine (N—S), 1,10-phenanthroline (N—N), bis(2-pyridylmethyl)sulphide (N—S—N), di-(2-picolyl)amine (N—N—N), pyridine-2,6-dicarboxylate (O—N—O2−) and 2,6-bis(methylthiomethyl)pyridine (S—N—S).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. G. Annibale B. Pitteri (2004) Inorg. Synth 34 76

    Google Scholar 

  2. L. Bauer L.A. Gardella (1963) J. Org. Chem 28 1323

    Google Scholar 

  3. H.J.J-B. Martel M. Rasmussen (1971) Tetrahedron Lett 41 3843 Occurrence Handle10.1016/S0040-4039(01)97304-6

    Article  Google Scholar 

  4. L. Canovese G. Chessa G. Marangoni B. Pitteri P. Uguagliati F. Visentin (1991) Inorg. Chim. Acta 186 79 Occurrence Handle10.1016/S0020-1693(00)87934-7

    Article  Google Scholar 

  5. G. Hill M.J. Irwin C.J. Levy L.M. Rendina R.J. Puddephatt (1998) Inorg. Synth 32 149

    Google Scholar 

  6. M.P. Brown, R.J. Puddephatt, M. Rashidi and K.R. Seddon, J. Chem. Soc. Dalton Trans., 951 (1977).

  7. S. Vianello M. Bonivento L. Cattalini O. Curcuruto P. Traldi (1991) Rapid Comm. Mass Spectromet 5 479 Occurrence Handle10.1002/rcm.1290051012

    Article  Google Scholar 

  8. F.A. Palocsay J.V. Rund (1968) Inorg. Chem 7 524

    Google Scholar 

  9. A. Baldo G. Chessa G. Marangoni B. Pitteri (1985) Polyedron 4 1429 Occurrence Handle10.1016/S0277-5387(00)86975-2

    Article  Google Scholar 

  10. L. Cattalini G. Chessa G. Marangoni B. Pitteri E. Celon (1989) Inorg. Chem 28 1944 Occurrence Handle10.1021/ic00309a034

    Article  Google Scholar 

  11. G. Annibale L. Cattalini G. Chessa G. Marangoni B. Pitteri M.L. Tobe (1985) Gazz. Chim. Ital 115 279

    Google Scholar 

  12. B. Pitteri L. Canovese G. Chessa G. Marangoni P. Uguagliati (1985) Polyedron 11 2363 Occurrence Handle10.1016/S0277-5387(00)83526-3

    Article  Google Scholar 

  13. B. Pitteri G. Marangoni L. Cattalini (1995) Polyhedron 14 2331 Occurrence Handle10.1016/0277-5387(95)00087-9

    Article  Google Scholar 

  14. J. Priest ParticleDe G.Y. Zheng C. Woods D.P. Rillema N.A. Mikirova M.E. Zandler (1997) Inorg. Chim. Acta 264 287 Occurrence Handle10.1016/S0020-1693(97)05688-0

    Article  Google Scholar 

  15. P.S.K. Chia S.E. Livingstone T.N. Lockyer (1966) Aust. J. Chem 19 1835

    Google Scholar 

  16. G. Chessa G. Marangoni B. Pitteri V. Bertolasi G. Gilli V. Ferretti (1991) Inorg. Chim. Acta 185 201 Occurrence Handle10.1016/S0020-1693(00)85445-6

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Bruno Pitteri.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Annibale, G., Bortoluzzi, M., Marangoni, G. et al. An Improved Method for the Preparation of Tetra-Coordinate Platinum(II) Chloro-Complexes Containing Bidentate or Terdentate Ligands Starting from cis/trans-[PtCl2(SMe2)2]. Transition Met Chem 30, 748–750 (2005). https://doi.org/10.1007/s11243-005-6275-5

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11243-005-6275-5

Keywords

Navigation