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Particle size distribution of inorganic and organic ions in coastal and inland Antarctic aerosol

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Abstract

The concentration and particle-size distribution of ionic species in Antarctic aerosol samples were determined to investigate their potential sources, chemical evolution, and transport. We analyzed aerosol samples collected at two different Antarctic sites: a coastal site near Victoria Land close to the Italian Research Base “Mario Zucchelli”, and another site located on the Antarctic plateau, close to Italian-French Concordia Research Station. We investigated anionic compounds using ion-chromatography coupled to mass spectrometry, and cationic species through capillary ion chromatography with conductometry. Aerosol collected close to the coast was mainly characterized by sea salt species such as Na+, Mg2+, and SO4 2−. These species represented a percentage of 88% of the total sum of all detected ionic species in the aerosol samples from the coastal site. These species were mainly distributed in the coarse fraction, confirming the presence of primary aerosol near the ocean source. Aerosol collected over the Antarctic plateau was characterized by high acidity, with nss-SO4 2−, NO3 −, and methanesulfonic acid as the most abundant species. These species were mainly distributed in the <0.49 μm fraction, and they had a behavior of a typical secondary aerosol, where several chemical and physical processes occurred.

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Acknowledgments

This work was financially supported by the Italian National Program of Antarctic Research (PNRA) through the project ‘Studio delle sorgenti e dei processi di trasferimento dell’ aerosol atmosferico antartico’ (no. 2009/A2.11). The research was also supported by the National Research Council of Italy (Consiglio Nazionale delle Ricerche, CNR). The authors thank ELGA LabWater for providing the Pure-Laboratory Option-R and Ultra Analytic, which produced the ultrapure water used in these experiments.

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  1. Department of Environmental Sciences, Informatics and Statistics, Ca’ Foscari University of Venice, Via Torino 155, 30172, Venice-Mestre, Italy

    Elena Barbaro, Sara Padoan, Torben Kirchgeorg, Giuseppa Toscano, Carlo Barbante & Andrea Gambaro

  2. Institute for the Dynamics of Environmental Processes CNR, Via Torino 155, 30172, Venice-Mestre, Italy

    Elena Barbaro, Roberta Zangrando, Giuseppa Toscano, Carlo Barbante & Andrea Gambaro

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  1. Elena Barbaro
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  2. Sara Padoan
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Correspondence to Elena Barbaro.

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Barbaro, E., Padoan, S., Kirchgeorg, T. et al. Particle size distribution of inorganic and organic ions in coastal and inland Antarctic aerosol. Environ Sci Pollut Res 24, 2724–2733 (2017). https://doi.org/10.1007/s11356-016-8042-x

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