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Role of vanadium and pyridine in heteropolycompounds for selective oxidation of alcohols with hydrogen peroxide

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Abstract

This study describes the application of heteropolyacids H3PMo12O40, H4SiMo12O40, H4PMo11VO40, H5PMo10V2O40, H9PMo6V6O40, and a hybrid pyridine-modified heteropolyacid with Keggin structure for selective oxidation of alcohols to ketones or aldehydes using aqueous hydrogen peroxide and acetonitrile as solvent. Performance of these different catalysts in 1-phenylethanol oxidation was studied. Influence of reaction temperature, amount of catalyst and hydrogen peroxide and reaction time on the yield of acetophenone was investigated to obtain optimal reaction conditions. Oxidation ability of the catalyst depended on the number of vanadium atoms present in the Keggin ion and to a lesser extent on pyridine substitution in the Keggin secondary structure. In order to explore the applicability of the method for selective oxidation of alcohols to ketones or aldehydes, various alcohols were investigated according to the general procedure using hybrid pyridine-modified heteropolyacid.

This study describes the application of heteropolyacids H3PMo12O40, H4SiMo12O40, H4PMo11VO40, H5PMo10V2O40, H9PMo6V6O40, and a hybrid pyridine-modified heteropolyacid with Keggin structure for selective oxidation of alcohols to ketones or aldehydes using aqueous hydrogen peroxide and acetonitrile as solvents.

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Acknowledgements

The authors thank Graciela Valle for the FTIR measurements and INCA, CONICET, ANPCyT and UNLP for their financial support.

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Authors and Affiliations

  1. Centro de Investigación y Desarrollo en Ciencias Aplicadas “Dr. Jorge J. Ronco” (CINDECA), Departamento de Química, Facultad de Ciencias Exactas, Universidad Nacional de La Plata-CCT-CONICET., Calle 47 Nro 257, B1900AJK, La Plata, Argentina

    VALERIA PALERMO, PAULA I VILLABRILLE, PATRICIA G VÁZQUEZ, CARMEN V CÁCERES & GUSTAVO P ROMANELLI

  2. Facultad de Ciencias Agrarias y Forestales, Universidad Nacional de La Plata., Calles 60 y 119 s/n, B1904AAN, La Plata, Argentina

    PAULA I VILLABRILLE & GUSTAVO P ROMANELLI

  3. Department of Environmental Science, Cà Foscari University, Dorsoduro 2137, 30123, Venice, Italy

    PIETRO TUNDO

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  1. VALERIA PALERMO
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  2. PAULA I VILLABRILLE
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  6. GUSTAVO P ROMANELLI
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Correspondence to GUSTAVO P ROMANELLI.

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PALERMO, V., VILLABRILLE, P.I., VÁZQUEZ, P.G. et al. Role of vanadium and pyridine in heteropolycompounds for selective oxidation of alcohols with hydrogen peroxide. J Chem Sci 125, 1375–1383 (2013). https://doi.org/10.1007/s12039-013-0523-6

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  • DOI: https://doi.org/10.1007/s12039-013-0523-6

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