A new platinum-based catalyst system for olefin asymmetric homogeneous hydroformylation

doi:10.1016/0022-328X(90)85320-X

Journal of Organometallic Chemistry

Volume 397, Issue 1, 23 October 1990, Pages 119-125

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Abstract

The complex [Pt(C₂H₄)((+)-DIOP)] interacts with [PtCl₂((+)-DIOP)] to give catalysts active in hydroformylation of styrene and 1-hexene. The activities of these systems depend upon the molar ratio of the two platinum complexes and the nature of the substrate. The systems display good chemioselectivity and induce asymmetry in the branched aldehydes formed. 2-Phenylpropanal can be isolated in ∼ 27% optical purity from hydroformylation of styrene.

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A new platinum-based catalyst system for olefin asymmetric homogeneous hydroformylation

Abstract

J. Organomet. Chem.

J. Organomet. Chem.

J. Organomet. Chem.

J. Organomet. Chem.

Bull. Chem. Soc. Jpn.

J. Chem. Soc., Chem. Commun.

J. Org. Chem.

J. Am. Chem. Soc.