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Aligned hexagonal ferrite fibres of Co2W, BaCo2Fe16O27 produced from an aqueous sol–gel process

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Abstract

Gel fibres of Co2W, BaCo2Fe16O27, were blow spun from an aqueous inorganic sol and collected as an aligned tow blanket with an alignment of over 90%. Upon calcination up to 1300°C, the ceramic fibres were shown by X-ray diffraction to form single-phase crystalline Co2W at 1200°C, an unusually low temperature for this compound to form as the major phase. The formation of Co2W was also accompanied by sudden grain growth, forming crystallites over 10 μm in length. While this reduced the mechanical strength of the fibres, they were still suitable for use in a composite material.

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References

  1. G. H. JONKER, H. P. WIJN and P. B. BRAUN, Phil. Techn. Rev. 18 (1956) 145.

    Google Scholar 

  2. P. B. BRAUN, Phil. Res. Rep. 12 (1957) 491.

    CAS  Google Scholar 

  3. J. J. WENT, G. W. RATHENAU, E. W. GORTER and G. W. van OOSTERHOUT, Phil. Techn. Rev. 13 (1952) 194.

    CAS  Google Scholar 

  4. D. SAMARAS, A. COLLOMB, S. HADJIVASILOU, C. ACHILLEOS J. TSOUKALAS, J. PANNETIER and J. RODRIGUEZ, J. Magn. Magn. Mater. 79 (1989) 193.

    Article  CAS  Google Scholar 

  5. A. COLLOMB, B. LAMBERT-ANDRON, J. X. BOUCHERLE and D. SAMARAS, Phys. Status. Solidi. A 96 (1986) 385.

    Article  CAS  Google Scholar 

  6. E. E. RICHES, “Ferrites” (Mills and Boon Technical Library, London, 1972) pp. 44–66.

    Google Scholar 

  7. W. H. von AULOCK and C. E. FAY, in “Linear Ferrite Devices for Microwave Applications”, edited by L. Marton (Academic Press, New York, 1968).

    Google Scholar 

  8. M. SUGIMOTO, in “Ferromagnetic Materials” vol. 3, edited by E. P. Wohlfarth (North-Holland Physics, Amsterdam, 1982) pp. 411 and 429.

    Google Scholar 

  9. Z. SIMSA, A. V. ZALESSKIJ and K. ZAVETA, Phys. Status. Solidi 14 (1966) 485.

    Article  CAS  Google Scholar 

  10. V. DEVENDER REDDY and P. VENUGOPAL REDDY, Phys. Status. Solidi. A 142 (1994) 451.

    Article  Google Scholar 

  11. H. STABLEIN, in “Ferromagnetic Materials” Vol. 3, edited by E. P. Wohlfarth (North-Holland Physics, Amsterdam, 1982) pp. 462–535.

    Google Scholar 

  12. S. RAM and J. C. JOUBERT, J. Magn. Magn. Mater. 99 (1991) 133.

    Article  CAS  Google Scholar 

  13. Idem, IEEE Trans. MAG-28 (1992) 15.

    Google Scholar 

  14. M. A. VINIK, Russ. J. Inorg. Chem. 10 (1965) 1164.

    Google Scholar 

  15. J. DROBNEK, W. C. BIGELOW and R. G. WELLS, J. Am. Ceram. Soc. 44 (1961) 262.

    Article  Google Scholar 

  16. R. L. COBLE, J. Appl. Phys. 32 (1961) 787.

    Article  CAS  Google Scholar 

  17. A. KELLY, “Strong Solids” (Clarendon Press, Oxford, 1973).

    Google Scholar 

  18. W. GRUNBERGER, B SPRINGMANN, M. BRUSBERG, M. SCHMIDT and R. JAHNKE, J. Magn. Magn. Mater. 101 (1991) 173.

    Article  Google Scholar 

  19. D. K. HALE, J. Mater. Sci. 11 (1976) 2105.

    Article  CAS  Google Scholar 

  20. H. A. GOLDBERG, US Pat 4725 490 (1988).

  21. M. J. MORTON, J. D. BIRCHALL and J. E. CASSIDY, (ICI) UK Pat 1360 200 (1974).

  22. S. I. KUZNETSOVA, E. P. NAIDEN and T. N. STEPANOVA, Inorg. Mater. 24 (1988) 856.

    Google Scholar 

  23. L. M. CASTELLIZ, K. M. KIM and P. S. BOUCHER, J. Can. Ceram. Soc. 38 (1969) 57

    CAS  Google Scholar 

  24. C. SURIG and K.A. HEMPEL, IEEE Trans. MAG-30 (1994) 997.

    Google Scholar 

  25. J. SMIT and H. P. J. WIJN, “Ferrites” (Philips Technical Library, Eindhoven, 1959) p. 221.

    Google Scholar 

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PULLAR, R.C., TAYLOR, M.D. & BHATTACHARYA, A.K. Aligned hexagonal ferrite fibres of Co2W, BaCo2Fe16O27 produced from an aqueous sol–gel process. Journal of Materials Science 32, 873–877 (1997). https://doi.org/10.1023/A:1018541314320

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  • DOI: https://doi.org/10.1023/A:1018541314320

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