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Evaluation of Trace Metal Fluxes to Soils in Hinterland of Porto Marghera Industrial Zone: Comparisons with Direct Measurements in the Lagoon of Venice

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Abstract

Trace metal (As, Cd, Cr, Ni, Hg, Pb) concentrations in soil samples collected around the Porto Marghera (Italy) industrial zone (2–40 km) near the city of Venice were compared with direct measurements of atmospheric deposition measured at comparable distances from the same source. Concentrations of Cd and Pb in soils decreased exponentially with increasing distance from the source; less clear signals were detected for As, Cr and Ni. Significant differences were found among the soils, which were partially resolved when their clay contents were normalised. Preliminary comparisons of fluxes of Cd and Pb derived from soil with direct deposition measurements showed increasing values with longer integration times. Annual Cd and Pb flux values of one year of direct deposition were 5 to 10 times lower than mean annual fluxes derived from soils,integrating 50 to 100 years. Values range from ∼0.1–0.4 to 1–2 mg m-2 yr-1 for Cd, and from 3–18 to 50–100 mg m-2 yr-1 for Pb. These results fit information on `historical' emission trends as recorded in sediments of the lagoon.

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References

  • Alloway, B. J. (ed.): 1995, Heavy Metals in Soils, 2nd ed., Blackie, Glasgow, pp. 378.

  • Baize, D.: 1997, Teneurs Totales en Éléments Traces Métalliques dans les Sols, INRA Editions, Paris, pp. 416.

  • Cochran, J. K., Frignani, M., Salamanca, M., Bellucci, L. G. and Guerzoni, S.: 1998, 'Lead-210 as a tracer of atmospheric inputs of heavy metals in the northern Venice Lagoon', Mar. Chem. 62, 15–29.

    Google Scholar 

  • Della Sala, S., Scazzola, R., Terrabujo, C., Giandon, P., Wenning, R. J., Dodge, D., Luksemburg, W. J. and Weagraff, S. A.: 1999, 'Assessment of PCDD/Fs, PCBs, and heavy metals in soil: A measure of the impact of the industrial zone of Porto Marghera on inland coastal areas of Italy', Organohalogen Comp. 43, 137–141.

    Google Scholar 

  • Di Domenico, A., Baldassarri, L. T., Ziemacki, D., De Felip, E., Ferri, F., Iacovella, M., La Rocca, C., Rodriguez, F., Volpi, F., Ferrari, G., Sansoni, R. and Settimo, G.: 1997, 'Selected carcinogenic organic microcontaminants and heavy metals in the Venice Lagoon', Organohalogen Comp. 34, 55–60.

    Google Scholar 

  • Giunta Regionale del Veneto: 1998, Ambiente, il Veneto Verso il 2000, Regione del Veneto, Venice, pp. 340 pp.

    Google Scholar 

  • Guerzoni, S., Molinaroli, E., Quarantotto, G. and Rampazzo, G.: 1995, 'Comparison of atmospheric and riverine fluxes of trace metals (Al, Cd, Cu, Fe, Ni, Pb) in the Lagoon of Venice', Plinius, 14, 177–179.

    Google Scholar 

  • Kabata-Pendias, A. and Pendias, H.: 1984, Trace Elements in Soils and Plants, CRC Press, Inc., Boca Raton, Florida, U.S.A., pp. 643.

    Google Scholar 

  • Magistrato alle Acque di Venezia: 1999, Attività per la Salvaguardia della Laguna di Venezia (Art. 3, L.798/1984) – Progetto Orizzonte 2023, Linea F, Consorzio Venezia Nuova, Venezia, pp. 722.

  • Ministero delle Risorse Agricole, Alimentari e Forestali: 1994, Metodi Ufficiali di Analisi Chimica del Suolo, Ministero delle Risorse Agricole, Roma, pp. 276.

  • Mosello, R., Marchetto, A. and Tartari, G. A.: 1988, 'Bulk and wet atmospheric deposition chemistry at Pallanza (N. Italy)', Water, Air, and Soil Pollut. 42, 137–145.

    Google Scholar 

  • Rossini, P., De Lazzari, A., Guerzoni, S., Molinaroli, E., Rampazzo, G. and Zancanaro, A.: 2001a, 'Atmospheric input of organic pollutants to the Venice Lagoon', Ann. Chim. (Rome) 91, 491–501.

    Google Scholar 

  • Rossini, P., Guerzoni, S., Rampazzo, G., Quarantotto, G., Garibbo, E., and Molinaroli, E.: 2001b, 'Atmospheric Deposition of Trace Metals in North Adriatic Sea', in E.M. Faranda, L. Guglielmo and G. Spezie (eds), Mediterranean Ecosystem, Structures and Processes, Springer-Verlag Italia, pp. 123–129.

    Google Scholar 

  • Scazzola, R., Avezzù, S., Biancotto, R., Chiamenti, E., Chiozzotto, E., Gerotto, M., Palonta, M. and Roiter, S.: 2003, 'Assessment of heavy metal background values in the soils of inland coastal areas of Venice, Italy', Ann. Chim. (Rome) 93, 465–470.

    Google Scholar 

  • Wenning, R. J., Dodge, D., Peck, B., Shearer, K., Luksemburg, W., Della Sala, S. and Scazzola, R.: 2000, 'Screening-level ecological risk assessment of polychlorinated dibenzo-p-dioxins and dibenzofurans in sediments and aquatic biota from the Venice Lagoon, Italy', Chemosphere 40, 1179–1197.

    Google Scholar 

  • WMO/UNEP-MAP: 1998, 'MED-POL Manual on Sampling and Analysis of Aerosols and Precipitation for Major Ions and Trace Elements', MAP Technical Report Series No. 123, UNEP, Athens, pp. 166.

    Google Scholar 

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Correspondence to Gabriele Matteucci.

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Scazzola, R., Matteucci, G., Guerzoni, S. et al. Evaluation of Trace Metal Fluxes to Soils in Hinterland of Porto Marghera Industrial Zone: Comparisons with Direct Measurements in the Lagoon of Venice. Water, Air, & Soil Pollution 153, 195–203 (2004). https://doi.org/10.1023/B:WATE.0000019945.13182.b0

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  • DOI: https://doi.org/10.1023/B:WATE.0000019945.13182.b0

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