Issue 7, 2008

Mild catalytic oxidation of secondary and tertiary amines to nitrones and N-oxides with H2O2 mediated by Pt(ii) catalysts

Abstract

Bridging hydroxo complexes of Pt(II) can be used as catalysts for the oxidation of tertiary and secondary amines under mild conditions using the environmentally benign hydrogen peroxide as the oxidant. The reaction proceeds with medium to excellent yields particularly in the case of the more electron rich tertiary amines.

Graphical abstract: Mild catalytic oxidation of secondary and tertiary amines to nitrones and N-oxides with H2O2 mediated by Pt(ii) catalysts

Article information

Article type
Paper
Submitted
01 Apr 2008
Accepted
08 May 2008
First published
13 Jun 2008

Green Chem., 2008,10, 793-798

Mild catalytic oxidation of secondary and tertiary amines to nitrones and N-oxides with H2O2 mediated by Pt(II) catalysts

M. Colladon, A. Scarso and G. Strukul, Green Chem., 2008, 10, 793 DOI: 10.1039/B805404E

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