Issue 24, 1984
From the journal:

Journal of the Chemical Society, Chemical Communications

Preparation and reactivity of iron(II) aryldi-imine derivatives

Gabriele Albertin,   Stefano Antoniutti  and  Emilio Bordignon  

Abstract

The hydride trans-[FeH(CO)L4]BPh4[L = P(OEt)3] reacts with aryldiazonium cations to give aryldi-imine [fe(NH[double bond, length half m-dash]NAr)-(CO)L4]2+ derivatives, which undergo substitution reactions with ketones, CO, RCN, and isonitriles to produce hexaco-ordinate cations [Fe{OC(RR′)}(CO)L4]2+, [Fe(CO)2L4]2+, [Fe(CO)(RCN)L4]2+, and [Fe(CO)(RNC)L42+ respectively, while in the reaction with gaseous NO the pentaco-ordinate complex {FeL4NO]+ is obtained.

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Article information

DOI
https://doi.org/10.1039/C39840001688
Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 1688-1689

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Preparation and reactivity of iron(II) aryldi-imine derivatives

G. Albertin, S. Antoniutti and E. Bordignon, J. Chem. Soc., Chem. Commun., 1984, 1688 DOI: 10.1039/C39840001688

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