Issue 59, 2014
From the journal:

RSC Advances

Behaviour of iprit carbonate analogues in solventless reactions†

F. Arico',‡a   S. Evaristo‡a  and  P. Tundo*a  

* Corresponding authors

a Green Chemistry Group, Department of Environmental Sciences, Informatics and Statistics, Ca' Foscari University of Venice, Dorsoduro 2137, Venezia 30123, Italy
E-mail: tundop@unive.it
Tel: +39 041234 8669

Abstract

Sulfur iprit carbonate analogues have been investigated in neat conditions at atmospheric pressure, in the presence and in the absence of a catalytic amount of base. Furthermore, their reaction mechanism has been discussed in detail. In these novel reaction conditions, sulfur mustard carbonate analogues, that previously showed poor or no reactivity, remarkably undergo efficient nucleophilic substitution with several substrates.

Graphical abstract: Behaviour of iprit carbonate analogues in solventless reactions

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Article information

DOI
https://doi.org/10.1039/C4RA03254C
Article type
Paper
Submitted
10 Apr 2014
Accepted
11 Jul 2014
First published
14 Jul 2014

RSC Adv., 2014,4, 31071-31078

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Behaviour of iprit carbonate analogues in solventless reactions

F. Arico', S. Evaristo and P. Tundo, RSC Adv., 2014, 4, 31071 DOI: 10.1039/C4RA03254C

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