Issue 10, 1981
From the journal:

Journal of the Chemical Society, Dalton Transactions

Synthesis, reactivity, and electrochemical behaviour of new five-co-ordinate nitrosyl cobalt complexes

Gabriele Albertin,   Emilio Bordignon,   Gian Antonio Mazzocchin,   Angelo A. Orio  and  Renato Seeber  

Abstract

The synthesis and characterization of some new five-co-ordinate mononitrosyl cobalt complexes of the type [CoL4(NO)][BPh4]2[L = P(OMe)3, P(OEt)3, or PPh(OEt)2] is described. The reactivity of these compounds with π-acceptor ligands such as NO, CO, phosphite, and isocyanide is discussed. Furthermore, the reaction with molecular oxygen and with halide ions (X–) has been investigated and a new method of obtaining the cations [CoXL3(NO)]+ has been achieved. The cathodic and anodic behaviour of the complex [Co{P(OEt)3}4(NO)][BPh4]2 at a platinum electrode in acetonitrile is also reported.

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Article information

DOI
https://doi.org/10.1039/DT9810002127
Article type
Paper

J. Chem. Soc., Dalton Trans., 1981, 2127-2131

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Synthesis, reactivity, and electrochemical behaviour of new five-co-ordinate nitrosyl cobalt complexes

G. Albertin, E. Bordignon, G. A. Mazzocchin, A. A. Orio and R. Seeber, J. Chem. Soc., Dalton Trans., 1981, 2127 DOI: 10.1039/DT9810002127

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