Issue 12, 1982

Electrochemical behaviour of dinitrosylbis(triethyl phosphite)-cobalt(I) tetraphenylborate in acetonitrile

Abstract

The electrochemical behaviour of the complex [Co{P(OEt)3}2(NO)2][BPh4] has been studied in acetonitrile, using platinum and mercury electrodes. It undergoes two subsequent reduction processes and a single oxidation process. In particular, the less cathodic one-electron reduction leads to the formation of the corresponding neutral species which is fairly stable in carefully deaerated solution.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1982, 2561-2562

Electrochemical behaviour of dinitrosylbis(triethyl phosphite)-cobalt(I) tetraphenylborate in acetonitrile

R. Seeber, G. Albertin and G. Mazzocchin, J. Chem. Soc., Dalton Trans., 1982, 2561 DOI: 10.1039/DT9820002561

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