Issue 44, 2013
From the journal:

RSC Advances

A water-soluble pyridyl-triazole ligand for aqueous phase palladium catalyzed Suzuki–Miyaura coupling†

Emanuele Amadio,a   Alberto Scrivanti,*a   Valentina Beghetto,a   Matteo Bertoldini,a   Md. Mahbubul Alama  and  Ugo Matteolia  

* Corresponding authors

a Department of Molecular Science and Nanosystems, Università Ca' Foscari Venezia, Venice, Italy
E-mail: scrivanti@unive.it
Fax: +39 041 2348917
Tel: +39 041 2348903

Abstract

An environmentally friendly water-soluble ligand has been prepared by “clicking” 2-(azidomethyl)pyridine with but-3-ynyl sodium sulphate. In situ combination of the new ligand with [Pd(η3-C3H5)Cl]2 (Pd : ligand = 1 : 1) provides a highly active catalytic system for the Suzuki–Miyaura reaction. Coupling of phenylboronic acid with a variety of aryl or heteroaryl bromides is carried out at catalyst loadings of 0.01% or lower under conventional heating. The aqueous catalytic phase may be used three times without loss of activity.

Graphical abstract: A water-soluble pyridyl-triazole ligand for aqueous phase palladium catalyzed Suzuki–Miyaura coupling

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Article information

DOI
https://doi.org/10.1039/C3RA44740E
Article type
Paper
Submitted
18 Jul 2013
Accepted
10 Sep 2013
First published
11 Sep 2013

RSC Adv., 2013,3, 21636-21640

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A water-soluble pyridyl-triazole ligand for aqueous phase palladium catalyzed Suzuki–Miyaura coupling

E. Amadio, A. Scrivanti, V. Beghetto, M. Bertoldini, Md. M. Alam and U. Matteoli, RSC Adv., 2013, 3, 21636 DOI: 10.1039/C3RA44740E

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