Solid state electrochemiluminescence from homogeneous and patterned monolayers of bifunctional spirobifluorene

Sergej Kudruk; Elena Villani; Federico Polo; Sebastian Lamping; Martin Körsgen; Heinrich F. Arlinghaus; Francesco Paolucci; Bart Jan Ravoo; Giovanni Valenti; Fabio Rizzo

doi:10.1039/C8CC02066C

Solid state electrochemiluminescence from homogeneous and patterned monolayers of bifunctional spirobifluorene†

Sergej Kudruk,^a Elena Villani,

^b Federico Polo,

^c Sebastian Lamping,^a Martin Körsgen,^d Heinrich F. Arlinghaus,^d Francesco Paolucci,

^b Bart Jan Ravoo,

^a Giovanni Valenti

*^b and Fabio Rizzo

*^ae

Author affiliations

* Corresponding authors

^a Organic Chemistry Institute and CeNTech, Westfälische Wilhelms-Universität Münster, Corrensstrasse 40, 48149 Münster, Germany

^b Department of Chemistry “G. Ciamician”, University of Bologna, via Selmi 2, 40126 Bologna, Italy
E-mail: g.valenti@unibo.it

^c National Cancer Institute-CRO Aviano, via F. Gallini 2, 33081 Aviano, Italy

^d Physics Institute, Westfälische Wilhelms-Universität Münster, Wilhelm-Klemm-Strasse 10, 48149 Münster, Germany

^e Institute of Molecular Science and Technologies (ISTM), National Research Council (CNR) and INSTM, via Golgi 19, 20133 Milano, Italy
E-mail: fabio.rizzo@cnr.it

Abstract

Electrochemiluminescence (ECL) generated by a monolayer of a spirobifluorene derivative covalently bound onto an indium tin oxide (ITO) substrate is reported for the first time. Our approach allows the efficient preparation homogeneous and patterned substrates through micromolding in capillaries (MIMIC), and opens novel scenarios for multicolour ECL applications.

Chemical Communications

Solid state electrochemiluminescence from homogeneous and patterned monolayers of bifunctional spirobifluorene†

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Solid state electrochemiluminescence from homogeneous and patterned monolayers of bifunctional spirobifluorene

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