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Complex viscosity behavior and cluster formation in attractive colloidal systems

F. Mallamace, S. H. Chen, A. Coniglio, L. de Arcangelis, E. Del Gado, and A. Fierro
Phys. Rev. E 73, 020402(R) – Published 22 February 2006

Abstract

The increase in viscosity that is observed in attractive colloidal systems by varying the temperature or the volume fraction can be related to the formation of structures due to particle aggregation. In particular we have studied the nontrivial dependence of the viscosity from the temperature and the volume fraction in the copolymer-micellar system L64. The comparison of the experimental data with the results of numerical simulations in a simple model for gelation phenomena suggests that this intriguing behavior can be explained in terms of cluster formation and that this picture can be quite generally extended to other attractive colloidal systems.

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  • Received 3 March 2005

DOI:https://doi.org/10.1103/PhysRevE.73.020402

©2006 American Physical Society

Authors & Affiliations

F. Mallamace1,2, S. H. Chen1, A. Coniglio3,6, L. de Arcangelis4, E. Del Gado5, and A. Fierro3,6

  • 1Department of Nuclear Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA
  • 2Dipartimento di Fisica and INFM, Università di Messina, I-98166, Messina, Italy
  • 3Dipartimento di Scienze Fisiche, Università di Napoli “Federico II,” Complesso Universitario di Monte Sant’Angelo, via Cintia 80126 Napoli, Italy
  • 4Dipartimento di Ingegneria dell’Informazione, Seconda Università di Napoli and CNISM, 81031 Aversa (Caserta), Italy
  • 5Laboratoire des Verres, Université Montpellier II, 34095 Montpellier, France
  • 6Coherentia CNR-INFM, Naples, Italy

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Issue

Vol. 73, Iss. 2 — February 2006

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