Electronic structure of intertwined kagome, honeycomb, and triangular sublattices of the intermetallics MCo2Al9 (M = Sr, Ba)

Chiara Bigi, Sahar Pakdel, Michał J. Winiarski, Pasquale Orgiani, Ivana Vobornik, Jun Fujii, Giorgio Rossi, Vincent Polewczyk, Phil D. C. King, Giancarlo Panaccione, Tomasz Klimczuk, Kristian Sommer Thygesen, and Federico Mazzola
Phys. Rev. B 108, 075148 – Published 21 August 2023

Abstract

Intermetallics are an important playground to stabilize a large variety of physical phenomena, arising from their complex crystal structure. The ease of their chemical tunabilty makes them suitable platforms to realize targeted electronic properties starting from the symmetries hidden in their unit cell. Here, we investigate the family of the recently discovered intermetallics MCo2Al9 (M=Sr, Ba) and we unveil their electronic structure. By using angle-resolved photoelectron spectroscopy and density functional theory calculations, we discover the existence of Dirac-like dispersions as ubiquitous features in this family, coming from the hidden kagome and honeycomb symmetries embedded in the unit cell. Finally, from calculations, we expect that the spin-orbit coupling is responsible for opening energy gaps in the electronic structure spectrum, which also affects the majority of the observed Dirac-like states. Our study constitutes an experimental observation of the electronic structure of MCo2Al9 and proposes these systems as hosts of Dirac-like physics with intrinsic spin-orbit coupling. The latter effect suggests MCo2Al9 as a future platform for investigating the emergence of nontrivial topology.

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  • Received 24 January 2023
  • Revised 28 May 2023
  • Accepted 21 July 2023

DOI:https://doi.org/10.1103/PhysRevB.108.075148

©2023 American Physical Society

Physics Subject Headings (PhySH)

Condensed Matter, Materials & Applied Physics

Authors & Affiliations

Chiara Bigi1,2,*, Sahar Pakdel3, Michał J. Winiarski4, Pasquale Orgiani5, Ivana Vobornik5, Jun Fujii5, Giorgio Rossi5,6, Vincent Polewczyk5, Phil D. C. King1, Giancarlo Panaccione5, Tomasz Klimczuk4, Kristian Sommer Thygesen3,†, and Federico Mazzola7,5,‡

  • 1SUPA, School of Physics and Astronomy, University of St Andrews, St Andrews KY16 9SS, United Kingdom
  • 2Synchrotron SOLEIL, F-91190 Saint-Aubin, France
  • 3CAMD, Department of Physics, Technical University of Denmark, DK-2800 Kongens Lyngby, Denmark
  • 4Faculty of Applied Physics and Mathematics, Advanced Materials Centre, Gdansk University of Technology, Narutowicza 11/12, PL-80-233 Gdansk, Poland
  • 5Istituto Officina dei Materiali (IOM)-CNR, Laboratorio TASC, Area Science Park, S.S.14, Km 163.5, I-34149 Trieste, Italy
  • 6Department of Physics, University of Milano, I-20133 Milano, Italy
  • 7Department of Molecular Sciences and Nanosystems, Ca' Foscari University of Venice, I-30172 Venice, Italy

  • *chiara.bigi@synchrotron-soleil.fr
  • thygesen@fysik.dtu.dk
  • federico.mazzola@unive.it

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Issue

Vol. 108, Iss. 7 — 15 August 2023

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