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Hydroethoxycarbonylation of α-olefins at low pressure of carbon(II) oxide in the presence of the PdCl2(PPh3)2–PPh3–AlCl3 system

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Abstract

High catalytic activity of the PdCl2(PPh3)2–PPh3–AlCl3 system containing AlCl3 as promotor has been demonstrated in the reaction of hydroethoxycarbonylation of hexene-1 and octene-1 at low pressure of carbon(II) oxide (≤25 atm). The reaction yields linear and branched products. The optimal conditions of the process have been elaborated. The target products yield is 84.6–93.8%.

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Authors and Affiliations

  1. Al-Farabi Kazakh National University, ul. Tole Bi 96A, Almaty, 050012, Kazakhstan

    Kh. A. Suerbaev & N. Zh. Kudaibergenov

  2. Ca’Foscari University of Venice, Venice, Italy

    A. Vavasori

Authors
  1. Kh. A. Suerbaev
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  2. N. Zh. Kudaibergenov
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  3. A. Vavasori
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Correspondence to Kh. A. Suerbaev.

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Original Russian Text © Kh.A. Suerbaev, N.Zh. Kudaibergenov, A. Vavasori, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 4, pp. 574–579.

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Suerbaev, K.A., Kudaibergenov, N.Z. & Vavasori, A. Hydroethoxycarbonylation of α-olefins at low pressure of carbon(II) oxide in the presence of the PdCl2(PPh3)2–PPh3–AlCl3 system. Russ J Gen Chem 87, 707–712 (2017). https://doi.org/10.1134/S1070363217040089

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  • DOI: https://doi.org/10.1134/S1070363217040089

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