Simulation of BIPV system performance is usually based on a Plane-Of-Array method, adopted from classical PV plant systems, to estimate power generation. This methods is very limited for simulating facades in complex urban environments, such as dense urban areas, as it uses simplified near-field shading to estimate system losses. Furthermore, this approach accounts only for PV electricity yield generation, while neglecting other architectural criteria like daylighting, especially important in case of semi transparent PV facade. For the purposes of complex BIPV facades, other methods, such as ray tracing, are more preferable. Therefore, this research aims to estimate capabilities and accuracy of RADIANCE ray tracing engine to calculate daylighting and irradiance on PV surface. Validation procedure has been carried out for complex BIPV façade module, composed of complex profiled glass tile and semi-transparent Dye-Sensitized Solar Cells. Results showed reasonably good agreement between simulation and experimental measurements, which proves that method is capable for being used for the general purposes of complex BIPV systems.